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All published articles 1032

Metal Distribution along the Major Roads of Trans-Amadi Industrial Complex Port Harcourt, Nigeria

P. E. Omuku, H. O. Abugu, S. C. Edeme & U. C. Umeobika · International Research Journal of Pure and Applied Chemistry · 2015

Topsoil samples were collected along six major roads within Trans-amadi industrial complex within the period of April to May. The pH of the soil had a range of 7.2 to 8.1, while moisture content had a range of 0.3% to 0.9%. Fe was seen to have higher concentration in all the soil...

Open access Research Article 10.9734/IRJPAC/2016/21492

Equilibria of Fe(II) and Fe(III) Solvent Extraction from Nitric Acid with Bis(salicylidene)ethylenediamine

F. S. Nworie, F. I. Nwabue, W. J. O. Oti, S. P. I. Ogah & S. Eluu · International Research Journal of Pure and Applied Chemistry · 2015

The equilibria of iron (II) and iron (III) extraction with bis(salicylidene) ethylenediamine dissolved in chloroform as non polar diluents from nitric acid solutions were studied in order to develop a chemical based conditions for determining the equilibrium distribution ratios....

Open access Research Article 10.9734/IRJPAC/2016/20005

Volumetric Thermodynamic Properties of Aqueous Binary Mixtures of Some Alkanols at Different Temperatures

Farid I. El-Dossoki · International Research Journal of Pure and Applied Chemistry · 2015

The densities of aqueous binary mixtures of some alkanols (1-butanol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol and 1,2,4-butanetriol including those of the pure liquids, over a wide composition range of alkanols at temperatures of 293.15, 298.15, 303.15, 308...

Open access Research Article 10.9734/IRJPAC/2016/21863

Synthesis of New 1,2,4-Triazoles Containing Oxadiazole Moiety: Potential Intermediates for Preparation of Ribavirin Analogues

Tatyana Sharonova, Sergey Baykov & Mikhail Dorogov · International Research Journal of Pure and Applied Chemistry · 2015

In this paper, we report synthesis of the new biheterocycles containing 1,2,4-triazole and 1,2,4-oxadiazole or 1,3,4-oxadiazole moiety. Oxadiazole ring is bioisosteric replacement of carboxamide group. In future, these compounds will be used for enzymatic synthesis of ribavirin a...

Open access Research Article 10.9734/IRJPAC/2016/22429

Effective Removal of Chromium (VI) Ions from Tannery Effluent using Chitosan-Alumina Composite

Mrinal Kanti Kabiraz, Ismet Ara Jahan, Shah Md. Masum, Md. Monarul Islam, S. M. Mahmudul Hassan, Badhan Saha & Husna Purvin Nur · International Research Journal of Pure and Applied Chemistry · 2015

A chitosan-alumina composite was prepared by coating chitosan, a glucosamine biopolymer, on activated alumina to remove chromium (VI) ion from tannery effluent. Chitosan was prepared from by demineralization and deproteinization of indigenous shrimp shell collected from Khulna, B...

Open access Research Article 10.9734/IRJPAC/2016/21856

An Investigation of Atomic Short Range Order (SRO) in Binary Ni20Pd80 and Au25Pd75 Alloy

Syed Kamran Ajmal, Amer Bashir Ziya, Ramiza ., Nausheen Syed, Saleem Akhter & Tahir Bashir · International Research Journal of Pure and Applied Chemistry · 2015

The atomic short range order (SRO) parameters (αi) have been investigated in polycrystalline alloys i.e., Ni20Pd80 and Au25Pd75. The Ni20Pd80 alloy was annealed at different temperatures (100 to 600°C) then studied with X-ray diffraction (XRD). The electronic theory of atomic sho...

Open access Research Article 10.9734/IRJPAC/2016/20030

Micelle-mediating Extraction Combined with Visible Spectrophotometry for the Determination of Ultra Trace Amounts of Bendiocarb Insecticide in Various Matrices after Oxidative Coupling with O-Toluidine

Zuhair A-A Khammas & Suher S. Ahmad · International Research Journal of Pure and Applied Chemistry · 2015

Aims: To develop a new eco-friendly method for the extraction and pre-concentration of Bendiocarb (BC) in real samples by using micelle-mediating extraction (MME) coupled with visible spectrophotometry after oxidative coupling with O-Toluidine. Study Design: All factors affecting...

Open access Research Article 10.9734/IRJPAC/2016/21948

Spatial Distribution and Speciation of Heavy Metals in Sediment of River Ilaje, Nigeria

Akinnawo Solomon, Kolawole Rasheed & Edward Olanipekun · International Research Journal of Pure and Applied Chemistry · 2015

Speciation of heavy metals (Zn, Fe, Cr, Cd, Cu and Pb) was carried out on the top and bottom sediment samples of two sampling sites in river Ilaje, Nigeria during the dry and rainy seasons. The samples were subjected to sequential extraction method and the extracts were analyzed...

Open access Research Article 10.9734/IRJPAC/2016/22031

Risk Assessment of Polycyclic Aromatic Hydrocarbons PAHs in Soils and Tubers Crops Collected from Ikot Oborenyin, South-south Nigeria

Moses Eno Anietie & Etim Victoria Godwin · International Research Journal of Pure and Applied Chemistry · 2015

Aims: This study aimed to investigate the levels, patterns sources and health risk of Polycyclic Aromatic Hydrocarbons (PAH) in soils and root crops of Ikot Oborenyin, Nigeria. Study Design: Samples were collected from two sites; the study and control sites. At each site, a plot...

Open access Research Article 10.9734/IRJPAC/2016/20154

Survey of Efficiency Agricultural Waste as Adsorbent for Removal of P-Cresol from Aqueous Solution

Davoud Balarak & Yousef Mahdavi · International Research Journal of Pure and Applied Chemistry · 2015

This study was conducted to evaluate the feasibility of P-Cresol removal from aqueous solutions using canola stalk. The effect of Contact time, Concentration of P-Cresol, biomass dosage and pH on adsorption of P-Cresol by canola biomass were also evaluated. The results showed tha...

Open access Research Article 10.9734/IRJPAC/2016/20507

Thermodynamic Calculation and 3d Modeling of the Liquidus Surface of the YbTe–Sb2Te3– Bi2Te3 System

A. N. Mamedov, E. R. Tagiev, L. F. Mashadiyeva & M. B. Babanly · International Research Journal of Pure and Applied Chemistry · 2015

The calculation and 3D modeling of the partial Gibbs free energy and YbTe liquidus, as well as the crystallization surface of solid solutions based on (Sb2Te3)y(Bi2Te3)1-y in the ternary YbTe-Sb2Te3-Bi2Te3 system were carried out by using the equations of thermodynamics of non-mo...

Open access Research Article 10.9734/IRJPAC/2016/21890

Desulphurization of Tawke Diesel Fuel by Adsorption on Na-Y Type Zeolite, Local Clay and Active Carbon

Mohammed K. Younis & Sherwan Mohammed Simo · International Research Journal of Pure and Applied Chemistry · 2015

The removal of sulfur compounds from Tawke diesel fuel is processed by the use of granular Na-Y type zeolite, MOR type zeolite, molecular sieve 3A type, local clay and activated charcoal. The results are characterized by sulfur meter and infrared spectroscopy to improve the resul...

Open access Research Article 10.9734/IRJPAC/2016/18119

N-Chloroamines as Oxidants: A Swern-type Oxidation at Room Temperature without Addition of Excess Base

Diane Kühn & Richard Göttlich · International Research Journal of Pure and Applied Chemistry · 2015

A new selective oxidation reaction for the oxidation of alcohols to aldehydes and ketones is described. N-Chloramines are used as the oxidant together with dialkylsulfide. This Swern-type reaction can be performed at room temperature without an additional base and the dialkylsulf...

Open access Research Article 10.9734/IRJPAC/2016/20573

Theoretical Study of the Efficiency of Some Nitro Benzenamine Derivatives in Acidic Medium to Serve as Excellent Organic Corrosion Inhibitors of Mild Steel

I. A. Adejoro, F. K. Ojo & J. A. Lori · International Research Journal of Pure and Applied Chemistry · 2015

A quantum chemical study of the efficiency of some nitro benzenamine derivatives as corrosion inhibitors of mild steel in acidic medium was investigated. Density Functional Theory (DFT) at the B3LYP/6-31G* level was used for the calculation. The calculated quantum chemical parame...

Open access Research Article 10.9734/IRJPAC/2016/20772

Preparation of Ternary (Ni3Pb2S2) Thin Films by Chemical Bath Deposition Method

S. M. Ho · International Research Journal of Pure and Applied Chemistry · 2015

In this work, the synthesis of Ni3Pb2S2 thin films using chemical bath deposition method was carried out. The films were deposited onto glass substrate from aqueous solutions in the absence of complexing agent. The atomic force microscopy analysis showed that the non-uniformity s...

Open access Research Article 10.9734/IRJPAC/2016/20775