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All published articles 1056

Fe0.2Al1.8Zn1O4 Composite: An Efficient Catalyst for the Synthesis of 1, 4-Dihydropyridine Derivatives

Vijay Kumar M. Joshi, Sunil U. Tekale, Sushama S. Kauthale, Sanjay K. Vyawahare, Ashok M. Zine, Sunita B. Shinde, K. L. Ameta & Rajendra P. Pawar · Chemical Science International Journal · 2014

A simple and rapid protocol has been developed for the synthesis of 1, 4-dihydropyridine derivatives in short reaction time to afford the products in excellent yield. Operational simplicity, clean reaction, high yield, simple work up are the significant advantages of the present...

Open access Research Article 10.9734/ACSJ/2014/4957

Removal of Congo Red Dye Using an Adsorbent Prepared from Martynia annua, L. Seeds

V. Sivakumar, M. Asaithambi, P. Sivakumar & N. Gopal · Chemical Science International Journal · 2014

Activated carbons M1 and M2 were prepared from the seeds of Martynia annua, L. using H2SO4 and H3PO4 as chemical activating agents respectively. In this study, utilization of these adsorbents for the removal of Congo red (CR) dye from aqueous solution was investigated. The physic...

Open access Research Article 10.9734/ACSJ/2014/6680

Possessions of Chemical Reaction on MHD Heat and Mass Transfer Nanofluid Flow on a Continuously Moving Surface

Md. Shakhaoath Khan, Ifsana Karim & Md. Sirajul Islam · Chemical Science International Journal · 2014

A two-dimensional steady flow of an electrically conducting, viscous incompressible nanofluid past a continuously moving surface is considered in the presence of uniform transverse magnetic field with chemical reaction. A mathematical governing model has developed for the momentu...

Open access Research Article 10.9734/ACSJ/2014/5422

High Sensitive and Selective Spectrophotometric Method for the Determination of Trace Level of Manganese in Some Real, Environmental, Biological, Soil, Food, Fertilizer and Pharmaceutical Samples Using Bis(2-hydroxy-1-naphthaldehyde) Orthophenylenediamin

M. Jamaluddin Ahmed, M. Tazul Islam & Shahanaz Parvin Lucky · Chemical Science International Journal · 2014

A very simple, ultra-sensitive and highly selective non-extractive spectrophotometric method is present for the determination of manganese at trace level using bis(2-hydroxy-1-napthaldehyde) orthophenylenediamine (HNA-OPD-HNA) has been proposed as new analytical reagent for the d...

Open access Research Article 10.9734/ACSJ/2014/7313

Kinetics and Mechanism of Palladium (II) Catalyzed Oxidation of D-(+) Galactose by Cerium(IV) in Aqueous Acidic Medium

Manoj Kumar Ghosh & S. K. Rajput · Chemical Science International Journal · 2014

Kinetics of palladium (II) catalyzed oxidation of D-(+) galactose by cerium (IV) have been studied titrimetrically in aqueous acidic medium in the temperature range 308-333 K. The reaction has been found to be first order with respect to D-(+) galactose in catalyzed reactions. Th...

Open access Research Article 10.9734/ACSJ/2014/7223

Chemical, Functional Properties and Amino Acid Composition of Raw and Defatted Cashew Kernel (Anacardium occidentale)

Ogungbenle Henry Niyi · Chemical Science International Journal · 2014

The proximate, minerals, anti nutrients, functional properties and amino acid of cashew kernel were studied. The results showed that the raw sample had high crude fat (48.1±0.5%), while the defatted sample had high crude protein (31.5±0.1%) and high crude fibre (4.21±0.01%). The...

Open access Research Article 10.9734/ACSJ/2014/7405

The Obtaining of Re-S Thin Films from Thiocarbamide Electrolytes and Influence of Various Factors on Alloy Composition

E. A. Salakhova, A. M. Aliyev & K. F. Ibraghimova · Chemical Science International Journal · 2014

The joint electrodeposition of rhenium and sulphur from thiocarbamide electrolyte was investigated in this study. By measuring the cycling volt-ampere curves the field of potentials, in the presence of which the joint electrodeposition of rhenium with sulphur takes place has been...

Open access Research Article 10.9734/ACSJ/2014/5878

The Effects of Conformational Changes on the Native Fluorescence of Aqueous Humic Materials

Leah Shaffer & Ray Von Wandruszka · Chemical Science International Journal · 2014

Aims: To elucidate the effect of induced conformational changes on the native fluorescence of aqueous humic materials. Study Design: The conformation of dissolved humates was changed by adjustment of a variety of environmental factors and the resulting fluorescence emission, exci...

Open access Research Article 10.9734/ACSJ/2014/7991

Isolation and Characterization of a Bioactive Phenylpropanoid from Ocimum sanctum L. Leaves through Chromatographic and Spectroscopic Methods

Supreet Upadhyaya, S. N. Tewari & Jashoda Behera · Chemical Science International Journal · 2014

Aims: This study aims at characterization of purified active ingredient isolated from commonly available botanical plant, Ocimum sanctum L. and to assess its potential for deployment in integrated disease management strategy of a staple food crop rice (Oryzae sativa L.) and rice...

Open access Research Article 10.9734/ACSJ/2014/6609

Analysis of Thermodynamics, Kinetics and Equilibrium Isotherm on Fe3+/Fe2+ Adsorption onto Palm Kernel Shell Activated Carbon (PKSAC): A Low-cost Adsorbent

Uzoije Atulegwu Patrick, Uche Cosmas Chinedu & Ashiegbu Darlington · Chemical Science International Journal · 2014

Adsorption of Fe3+/Fe2+ from a polluted shallow well water onto a palm kernel shell activated carbon (PKSAC) has been studied.  Batch experiment was adopted to study the Removal efficiency of Fe3+/Fe2+ on varying contact time, temperature, adsorbent loading and concentrations. Eq...

Open access Research Article 10.9734/ACSJ/2014/7149

Progress of Red Mud Utilization: An Overview

Harekrushna Sutar, Subash Chandra Mishra, Santosh Kumar Sahoo, Ananta Prasad Chakraverty & Himanshu Sekhar Maharana · Chemical Science International Journal · 2014

Red mud is a solid waste residue of the digestion of bauxite ores with caustic soda for alumina production. Its disposal remains a worldwide issue in terms of environmental concerns. During the past decades, extensive work has been done by a lot of researchers to develop various...

Open access Research Article 10.9734/ACSJ/2014/7258

Succinicate Bridged Polymeric Complexes of Copper (II) and Zinc (II) Acetylacetonate

Abdullahi Mustapha & Ladi Musa · Chemical Science International Journal · 2014

Cu(II) and Zn(II) salts were treated with 2,4-pentanedione to synthesize copper (II) acetylacetonate and zinc (II) acetylacetonate. These complexes were subsequently cross linked with succinate to produce corresponding bridged dimmers. The UV- visible spectrum of the complex show...

Open access Research Article 10.9734/ACSJ/2014/7529

Kinetics of Methylene Green and Ascorbic Acid Reaction in Aqueous 2-propanol at Different Temperatures

Zahida Khalid, Rehana Saeed, Fahim Uddin & Maria Ashfaq · Chemical Science International Journal · 2014

The kinetics of reaction of methylene green with ascorbic acid was carried out spectrophotometrically in mixed solvent system by using aqueous 2- propanol ratios as a solvent in the presence of hydrochloric acid. The pseudo-first order rate constants were proposed on the basis of...

Open access Research Article 10.9734/ACSJ/2014/7136

Electron Transfer Reaction of Pyridoxine (Vitamin B6) with Keggin Type 12 Tungstocobaltate (III) in Aqueous Perchlorate Medium

Sadhana Senapati, A. K. Patnaik, S. P. Das & P. Mohanty · Chemical Science International Journal · 2014

Transition metal substituted heteropolymetalates exhibit different chemical and electrochemical properties.  The complexes of transition metal ions with polyoxanions such as polytungstates are well known as outer-sphere electron transfer reagents. 12-tungstocobaltate (III) has th...

Open access Research Article 10.9734/ACSJ/2014/6880

The Reactions of Hydrochlorides of 2, 3-Tri (Tetra) Methylene-3, 4-Dihydropyrimidine-4-Ones with N-Bromosuccinimide and Bromine

N. I. Mukarramov, Kh. Z. Khakimova, A. O. Nasrullaev, Kh. U. Khodjaniyazov & Kh. M. Shakhidoyatov · Chemical Science International Journal · 2013

Aims: To carry out reactions between hydrochlorides of 2, 3-tri(tetra)methylene-3, 4-dihydropyrimidine-4-ones and N-bromosuccinimide (and/or bromine), to determine way of reactions. Study Design: Official design. Place and Duration of Study: Department of Organic Chemistry, Insti...

Open access Research Article 10.9734/ACSJ/2014/7060