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Research Article Open access CC BY 4.0

Bi-ZnO Heterogeneous Catalyst for Transesterification of Crude Jatropha Oil to Fatty Acid Methyl Ester

M. A. Olutoye, B. Suleiman, A. S. Yusuff

Advances in Research · pp. 1–8 · Published 12 Apr 2016

10.9734/AIR/2016/20716

Abstract

The transesterification of crude jatropha oil (CJO) to biodiesel using Bi-ZnO (bi-zinc oxide) as a solid catalyst was investigated. The catalyst was prepared by co-precipitation technique, calcined and characterized with XRD, TEM and the surface area, pore volume and pore size distribution of the developed catalyst were measured using BET method to give insights into its performance. It was established that sample loading of 2.0 wt.% Bi on ZnO could exhibit the highest catalytic activity when the transesterification reaction was carried out at reflux of methanol (65°C), with a 12:1 molar ratio of methanol to oil and a catalyst amount of 4 wt.%, the conversion of jatropha oil was 95%during 1 h of reaction. The utilization of the catalyst for transesterification of non-edible oil will reduce dependence on food-grade oil for industrial application. The catalyst when washed using methanol and oven dried at 80°C, can be reused for further tranesterification of the oil.

Biodiesel heterogeneous catalysis transesterification bismuth loading on ZnO

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Cited by 13

Synthesis of biodiesel via methanolysis of waste frying oil by biowaste-derived catalyst: process optimization and biodiesel blends characterization

Adeyinka S. Yusuff, Kudirat A. Thompson-Yusuff, Anselm I. Igbafe · Biomass Conversion and Biorefinery · 2022

Heterogeneous ZnO-containing catalysts for efficient biodiesel production

Anping Wang, Wenxuan Quan, Heng Zhang · RSC Advances · 2021

Synthesis and characterization of anthill‐eggshell‐Ni‐Co mixed oxides composite catalyst for biodiesel production from waste frying oil

Adeyinka S. Yusuff, Olalekan D. Adeniyi, Sarafa O. Azeez · Biofuels, Bioproducts and Biorefining · 2018

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