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Research Article Open access CC BY 4.0

N-Chloroamines as Oxidants: A Swern-type Oxidation at Room Temperature without Addition of Excess Base

Diane Kühn, Richard Göttlich

International Research Journal of Pure and Applied Chemistry · pp. 1–6 · Published 19 Sep 2015

10.9734/IRJPAC/2016/20573

Abstract

A new selective oxidation reaction for the oxidation of alcohols to aldehydes and ketones is described. N-Chloramines are used as the oxidant together with dialkylsulfide. This Swern-type reaction can be performed at room temperature without an additional base and the dialkylsulfide may be used catalytically.  

Oxidation aldehyde catalysis

Cited by 2

Alcohol Oxidation in the Presence of Methyl Chlorosulfonate and Dimethyl Sulfoxide

Yuriy A. Davidovich, S. V. Kozlov, Y. I. Smushkevich · ChemistrySelect · 2020

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