New Heat-Proof Methylphenylsiloxane Resins and High Temperature Resisting Enamels on Their Basis

O. G. Ryzhova; A. M. Kontorov; A. N. Polivanov; R. S. Mirgazitova; A. I. Katanaev

doi:10.9734/IRJPAC/2014/7257

Research Article Open access CC BY 3.0

New Heat-Proof Methylphenylsiloxane Resins and High Temperature Resisting Enamels on Their Basis

O. G. Ryzhova, A. M. Kontorov, A. N. Polivanov, R. S. Mirgazitova, A. I. Katanaev

International Research Journal of Pure and Applied Chemistry · pp. 520–530 · Published 15 May 2014

10.9734/IRJPAC/2014/7257

Abstract

New heat resistant methylphenylsiloxane resins produced by methyltriethoxysilane and oligophenylsilsesquioxane acidolysis were investigated. The synthesized resins are characterized by narrow molecular-mass distribution, higher thermal and thermal oxidative stability, reduced gelation period as compared to starting oligophenylsiloxane characteristics. Based on the produced resins high temperature resisting enamels with the improved properties: coating impact strength, heat resistance, proportional liquid (water, gasoline, industrial oil) action resistance were developed.

Methylphenylsiloxane resins oligosilsesquioxanes thermal and thermal oxidative stability 29Si 1Н NMR spectroscopy high temperature resisting enamels

References (4)

1 Substituent Effects on the Sol−Gel Chemistry of Organotrialkoxysilanes [DOI]
2 Synthesis, morphology, and properties of hydroxyl terminated‐POSS/polyimide low‐k nanocomposite films [DOI]
3 Characterization of negative-type photoresists containing polyhedral oligomeric silsesquioxane methacrylate [DOI]
4 SYNTHESIS, CHARACTAERIZATION AND COMPUTER SIMULATIONS OF STEREOREGULAR POLY-(METHYLPHENYLSILOXANE)

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O. G. Ryzhova, A. M. Kontorov, A. N. Polivanov, R. S. Mirgazitova, A. I. Katanaev (2014). New Heat-Proof Methylphenylsiloxane Resins and High Temperature Resisting Enamels on Their Basis. International Research Journal of Pure and Applied Chemistry , 520–530. https://doi.org/10.9734/IRJPAC/2014/7257

Affiliations

O. G. Ryzhova — State Scientific Center of the Russian Federation, Federal State Unitary Enterprise, State Research Institute for Chemistry and Technology of Organoelement Compounds, 38, shosse Entuziastov Moscow, Russia
A. M. Kontorov — State Scientific Center of the Russian Federation, Federal State Unitary Enterprise, State Research Institute for Chemistry and Technology of Organoelement Compounds, 38, shosse Entuziastov Moscow, Russia
A. N. Polivanov — State Scientific Center of the Russian Federation, Federal State Unitary Enterprise, State Research Institute for Chemistry and Technology of Organoelement Compounds, 38, shosse Entuziastov Moscow, Russia
R. S. Mirgazitova — Elkon JSC, 11 Kommunalnaya, Novocheboksarsk, Chuvash Republic, Russia
A. I. Katanaev — Elkon JSC, 11 Kommunalnaya, Novocheboksarsk, Chuvash Republic, Russia

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